 | Megumi Ogata als Shinji Ikari (voice) |
 | Megumi Hayashibara als Rei Ayanami / Yui Ikari (voice) |
 | Kotono Mitsuishi als Misato Katsuragi (voice) |
 | Yuko Miyamura als Asuka Langley Soryu (voice) |
 | Fumihiko Tachiki als Gendo Ikari (voice) |
 | Miki Nagasawa als Maya Ibuki (voice) |
 | Takehito Koyasu als Shigeru Aoba (voice) |
 | Hiro Yuuki als Makoto Hyouga (voice) |
 | Yuriko Yamaguchi als Ritsuko Akagi (voice) |
 | Motomu Kiyokawa als Kozo Fuyutsuki (voice) |
 | Akira Ishida als Kaworu Nagisa (voice) |
 | Mugihito als Keel Lorenz (voice) |
| Mitsuhisa Ishikawa | Producer |
| Sachiko Miki | Editor |
| Hideaki Anno | Writer |
| Hisao Shirai | Director of Photography |
| Hideyuki Tanaka | Sound Director |
| Hideaki Anno | Director |
| Kazuya Tsurumaki | Director |
| Shinji Higuchi | Storyboard Artist |
| Hiroshi Kato | Art Direction |
| Masayuki | Assistant Director |
| Mitsuharu Haibara | Visual Effects |
| Masao Shibata | Visual Effects |
| Hideaki Anno | Animation Director |
| Tadashi Hiramatsu | Animation Director |
| Shunji Suzuki | Animation Director |
| Miyuki Nanri | Line Producer |
| Tadashi Hiramatsu | Key Animation |
| Yoshiyuki Sadamoto | Character Designer |
| Kazuya Tsurumaki | Second Unit Director |
| Shiro Sagisu | Original Music Composer |
| Mitsuo Iso | Key Animation |
| Junichi Sato | Storyboard Artist |
| Hideaki Anno | Storyboard Artist |
| Takeshi Honda | Animation Director |
| Kazuchika Kise | Animation Director |
| Yoh Yoshinari | Key Animation |
| Miyako Yatsu | Key Animation |
| Noriko Morishima | Key Animation |
| Hideyuki Morioka | Key Animation |
| Yasushi Muraki | Key Animation |
| Kazuya Miura | Key Animation |
| Masayuki | Key Animation |
| Shoichi Masuo | Key Animation |
| Mahiro Maeda | Key Animation |
| Takeshi Honda | Key Animation |
| Hisaki Furukawa | Key Animation |
| Hidenori Fukuoka | Key Animation |
| Takuya Nonaka | Key Animation |
| Takehiro Noda | Key Animation |
| Kayoko Nabeta | Key Animation |
| Manabu Tanzawa | Key Animation |
| Shiho Takeuchi | Key Animation |
| Atsushi Takeuchi | Key Animation |
| Masahiro Sekiguchi | Key Animation |
| Shigeki Sunada | Key Animation |
| Kenji Shinohara | Key Animation |
| Masayuki Sato | Key Animation |
| Takayuki Goto | Key Animation |
| Toshio Kawaguchi | Key Animation |
| Yutaka Kamogawa | Key Animation |
| Nobutoshi Ogura | Key Animation |
| Tensai Okamura | Key Animation |
| Masahiko Ohkura | Key Animation |
| Kenji Irie | Key Animation |
| Isamu Imakake | Key Animation |
| Hiroyuki Imaishi | Key Animation |
| Takeshi Ito | Key Animation |
| Atsuko Ishida | Key Animation |
| Akiharu Ishii | Key Animation |
| Hideaki Anno | Key Animation |
| Masahiro Ando | Key Animation |
| Yuji Moriyama | Key Animation |
| Kazunobu Hoshi | Key Animation |
| Hisashi Hirai | Key Animation |
| Shinya Hasegawa | Key Animation |
| Takashi Hashimoto | Key Animation |
| Katsuichi Nakayama | Key Animation |
| Norimoto Tokura | Key Animation |
| Katsuyuki Tsubouchi | Key Animation |
| Hideki Takahashi | Key Animation |
| Koji Sugiura | Key Animation |
| Mamoru Sasaki | Key Animation |
| Takayuki Gorai | Key Animation |
| Mamoru Kurosawa | Key Animation |
| Kanta Kamei | Key Animation |
| Satoru Iriyoshi | Key Animation |
| Hideaki Anno | Original Film Writer |
