 | Rica Matsumoto als Satoshi (voice) |
 | Ikue Otani als Pikachu (voice) |
 | Mayuki Makiguchi als Serena (voice) |
 | Yuki Kaji als Citron / Puni-chan (voice) |
 | Mariya Ise als Eureka (voice) |
 | Megumi Satou als Dedenne (voice) |
 | Megumi Hayashibara als Musashi (voice) |
 | Shin-ichiro Miki als Kojiro (voice) |
 | Inuko Inuyama als Nyarth (voice) |
 | Yuji Ueda als Sonans (voice) |
 | Unsho Ishizuka als Narrator (voice) |
 | Matsumoto Kōshirō X als Volcanion (voice) |
 | Yuka Terasaki als Magearna (voice) |
 | Koichi Yamadera als Jarvis (voice) |
 | Mayu Matsuoka als Kimia (voice) |
 | Shoko Nakagawa als Racel (voice) |
 | Yasuyuki Kase als Dohga (voice) |
 | Kanako Toujou als Ether (voice) |
 | Tomomichi Nishimura als Éliphas (voice) |
 | Sanae Kobayashi als Flamel (voice) |
| Kunihiko Yuyama | Director |
| Atsuhiro Tomioka | Screenplay |
| Satoshi Tajiri | Original Concept |
| Ken Sugimori | Original Concept |
| Junichi Masuda | Original Concept |
| Miyuki Sato | Color Designer |
| Yumiko Kuga | Background Designer |
| Shinji Miyazaki | Original Music Composer |
| Shinsuke Ikeda | Director of Photography |
| Rika Murakami | Key Animation |
| Satoshi Nakano | Supervising Animation Director |
| Kazumi Sato | Supervising Animation Director |
| Kazuhiko Wanibuchi | Key Animation |
| Yukiko Watabe | Key Animation |
| Shinichi Wada | Key Animation |
| Masahiko Yoda | Key Animation |
| Fumiko Yoshida | Key Animation |
| Masahiro Yoshisaki | Key Animation |
| Shinichi Yoshikawa | Key Animation |
| Tomoko Yamada | Key Animation |
| Kohei Yanagida | Key Animation |
| Ayaka Yasumi | Key Animation |
| Etsuhito Mori | Key Animation |
| Kazue Motohiro | Key Animation |
| Takuji Mogi | Key Animation |
| Kazuaki Mori | Key Animation |
| Osamu Murata | Key Animation |
| Tadaaki Miyata | Key Animation |
| Hitomi Miyazaki | Key Animation |
| Nobuyuki Mitani | Key Animation |
| Miyuki Matsumoto | Key Animation |
| Norihiro Matsubara | Key Animation |
| Kyoko Matsubara | Key Animation |
| Shihomi Matsubayashi | Key Animation |
| Susumu Matsunaga | Key Animation |
| Sadatoshi Matsuzaka | Key Animation |
| Hirofumi Masuda | Key Animation |
| Hong Beom-seok | Key Animation |
| Hiroyuki Horiuchi | Key Animation |
| Taichi Furumata | Key Animation |
| Yoshikazu Fujiwara | Key Animation |
| Noriyuki Fukuda | Key Animation |
| Toshihiko Fukano | Key Animation |
| Koji Fukasawa | Key Animation |
| Naoki Hiramura | Key Animation |
| Daiki Handa | Key Animation |
| Hideo Harigaya | Key Animation |
| Issei Hasegawa | Key Animation |
| Yuki Hashimoto | Key Animation |
| Tsutomu Nishiyama | Key Animation |
| Hiromi Niioka | Key Animation |
| Hidetoshi Namura | Key Animation |
| Mayumi Nakamura | Key Animation |
| Nobuki Nakamura | Key Animation |
| Akiko Nakamura | Key Animation |
| Yuki Nakano | Key Animation |
| Tomoki Nakano | Key Animation |
| Asuka Nakaji | Key Animation |
| Akiko Nakata | Key Animation |
| Hiromi Nakagawa | Key Animation |
| Midori Nagaoka | Key Animation |
| Kiyomi Torii | Key Animation |
| Eiichi Tominaga | Key Animation |
| Daisuke Tsumagari | Key Animation |
| Shunichiro Taniguchi | Key Animation |
| Ryousuke Tanigawa | Key Animation |
| Ayu Tanaka | Key Animation |
| Masami Takebuchi | Key Animation |
| Kyoko Taketani | Key Animation |
| Kyouko Takeuchi | Key Animation |
| Tomoko Takei | Key Animation |
| Yuya Takahashi | Key Animation |
| Mizuka Takahashi | Key Animation |
| Hatsumi Takahashi | Key Animation |
| Mizuho Tajima | Key Animation |
| Koichi Taguchi | Key Animation |
| Ayano Suzuki | Key Animation |
| Sayuri Sakimoto | Key Animation |
| Toshiharu Sugie | Key Animation |
| Ayano Shimizu | Key Animation |
| Masahito Sawada | Key Animation |
| Kaori Saito | Key Animation |
| Tsuyoshi Sakai | Key Animation |
| Akemi Kobayashi | Key Animation |
| Nozomu Kuwashima | Key Animation |
| Chizuko Kusakabe | Key Animation |
| Izumi Kawada | Key Animation |
| Hiroyuki Kamura | Key Animation |
| Masato Kato | Key Animation |
| So Kato | Key Animation |
| Kenji Kato | Key Animation |
| Miwa Katayama | Key Animation |
| Hidetoshi Owashi | Key Animation |
| Kanako Ono | Key Animation |
| Kazumi Ono | Key Animation |
| Maiko Ochiai | Key Animation |
| Kazuhiro Ohmame | Key Animation |
| Akihiro Otake | Key Animation |
| Masanori Osawa | Key Animation |
| Yoshifumi Okawa | Key Animation |
| Hiroko Oguri | Key Animation |
| Erika Okada | Key Animation |
| Akihiko Oka | Key Animation |
| Shun Enokido | Key Animation |
| Kouichirou Ueda | Key Animation |
| Junji Uesugi | Key Animation |
| Satoru Iriyoshi | Key Animation |
| Kazuaki Imoto | Key Animation |
| Masahiko Itojima | Key Animation |
| Yasuhiro Ito | Key Animation |
| Yuri Ichinose | Key Animation |
| Sayuri Ichiishi | Key Animation |
| Shinji Itadaki | Key Animation |
| Shinsuke Ishikawa | Key Animation |
| Nozomi Ishii | Key Animation |
| Chisato Ikehira | Key Animation |
| Hiroki Ikeshita | Key Animation |
| Atsushi Aono | Key Animation |
| Akihito Aoki | Key Animation |
| Yo Miura | Storyboard Artist |
