 | Megumi Ogata als Shinji Ikari (voice) |
 | Megumi Hayashibara als Rei Ayanami / Yui Ikari (voice) |
 | Yuko Miyamura als Asuka Shikinami Langley (voice) |
 | Maaya Sakamoto als Mari Illustrious Makinami (voice) |
 | Kotono Mitsuishi als Misato Katsuragi (voice) |
 | Yuriko Yamaguchi als Ritsuko Akagi (voice) |
 | Koichi Yamadera als Ryoji Kaji (voice) |
 | Fumihiko Tachiki als Gendo Ikari (voice) |
 | Motomu Kiyokawa als Kozo Fuyutsuki (voice) |
 | Miki Nagasawa als Maya Ibuki (voice) |
 | Takehito Koyasu als Shigeru Aoba (voice) |
 | Hiro Yuuki als Makoto Hyuuga (voice) |
 | Tomokazu Seki als Toji Suzuhara (voice) |
 | Tetsuya Iwanaga als Kensuke Aida (voice) |
 | Junko Iwao als Hikari Horaki (voice) |
 | Mugihito als Keel Lorenz (voice) |
 | Joe Fria als Makoto Hyuga (voice) |
| Hideaki Anno | Screenplay |
| Shiro Sagisu | Original Music Composer |
| Hiroshi Kato | Art Direction |
| Hideaki Anno | Director |
| Toshimichi Otsuki | Executive Producer |
| Tadashi Hiramatsu | Key Animation |
| Hikaru Utada | Theme Song Performance |
| Takashi Hashimoto | Key Animation |
| Tetsuya Nishio | Key Animation |
| Kenichi Konishi | Key Animation |
| Akihiko Yamashita | Key Animation |
| Akemi Hayashi | Key Animation |
| Tomohiro Hirata | Key Animation |
| Takashi Mukouda | Key Animation |
| Takeshi Takakura | Key Animation |
| Akiko Asaki | Key Animation |
| Sachiko Okumura | Key Animation |
| Kiyotaka Oshiyama | Key Animation |
| Yasui Muroi | Key Animation |
| Atsushi Ikariya | Key Animation |
| Hiroaki Goda | Key Animation |
| Hideki Kakita | Key Animation |
| Fumio Iida | Key Animation |
| Ikuo Kuwana | Key Animation |
| Koji Haneda | Key Animation |
| Soichiro Matsuda | Key Animation |
| Shigeto Koyama | Key Animation |
| Ryota Furukawa | Key Animation |
| Masaharu Uemura | Key Animation |
| Sushio | Key Animation |
| Atsushi Nishigori | Key Animation |
| Yoh Yoshinari | Key Animation |
| Kazuhiro Takamura | Key Animation |
| Meiju Maeda | Key Animation |
| Iwao Teraoka | Key Animation |
| Akira Takata | Key Animation |
| Atsushi Tamura | Key Animation |
| Makiko Suzuki | Key Animation |
| Masafumi Yokota | Key Animation |
| Hitomi Hasegawa | Key Animation |
| Shinpei Kamata | Key Animation |
| Katsuhiko Kitada | Key Animation |
| Kazuchika Kise | Key Animation |
| Mahiro Maeda | Key Animation |
| Hideaki Anno | Key Animation |
| Kazuya Tsurumaki | Key Animation |
| Masayuki | Key Animation |
| Daizen Komatsuda | Key Animation |
| Katsuichi Nakayama | Key Animation |
| Shoichi Masuo | Key Animation |
| Shunji Suzuki | Key Animation |
| Hidenori Matsubara | Key Animation |
| Kazuko Kikuchi | Color Designer |
| Shunji Suzuki | Animation Director |
| Takeshi Honda | Animation Director |
| Hidenori Matsubara | Animation Director |
| Atsushi Okuda | Animation Director |
| Ikuto Yamashita | Mechanical Designer |
| Sayaka Koiso | Animation |
| Kazuya Tsurumaki | Storyboard Artist |
| Shinji Higuchi | Storyboard Artist |
| Masaki Tachibana | Storyboard Artist |
| Junichi Sato | Storyboard Artist |
| Sayo Yamamoto | Storyboard Artist |
| Tatsuya Kushida | Art Direction |
| Souichi Masui | Storyboard Artist |
| Atsushi Nishigori | Storyboard Artist |
| Hiroaki Goda | Storyboard Artist |
| Daizen Komatsuda | Storyboard Artist |
| Katsuichi Nakayama | Storyboard Artist |
| Masayuki | Storyboard Artist |
| Hideaki Anno | Storyboard Artist |
| Yuka Hirama | Background Designer |
| Ryouka Kinoshita | Background Designer |
| Naoko Yamada | Background Designer |
| Michie Suzuki | Background Designer |
| Nguyen Cuc | Background Designer |
| Yoshiyuki Sadamoto | Character Designer |
| Aya Sato | Background Designer |
| Tatsuya Tanaka | Key Animation |
| Daizen Komatsuda | Assistant Director |
| Katsuichi Nakayama | Assistant Director |
| Yu Wakabayashi | Compositing Artist |
| Atsushi Okuda | Key Animation |
| Takeshi Honda | Key Animation |
| Masayuki | Director |
| Kazuya Tsurumaki | Director |
| Hideaki Anno | Original Film Writer |
| Akio Satsukawa | Co-Writer |
| Yoji Enokido | Co-Writer |
| Shinji Higuchi | Co-Writer |
| Ryotaro Yoshikawa | Co-Writer |
| Taiki Sakurai | Co-Writer |
| Hideaki Anno | Writer |
| Kazuya Tsurumaki | Co-Director |
| Masayuki | Co-Director |
